A.3.2 Secondary and Case Fabrication

This alternative involves those activities required to support the production and maintenance of the secondaries and case components of the nuclear weapons physics package as follows: 

Functional capabilities required to perform these activities include operations to physically and chemically process, machine, inspect, assemble, certify, disassemble, and store secondary materials. Management of wastes generated from these operations is also required. The fabrication of secondaries and cases can be subdivided into the following major material production processes: uranium, lithium, and nonnuclear/special materials. The following typical process descriptions are provided to illustrate the functional activities and operations associated with each of the major production processes. These processes are based on traditional secondary and case fabrication methods and represent upper bounds to the types and number of processes that would be continued in the downsized and reconfigured Complex. Alternative sites for performing secondary and case fabrication are Y-12, LANL, and LLNL. The site-specific descriptions provided in sections A.3.2.1 to A.3.2.3 are based on more streamlined and less unit operations than described in this section. When comparing data between site alternatives, it is important to note that there are differences in the facility designs. The Y-12 alternative considers all the necessary support facilities to conduct the missions, not just the production and storage facilities. The LANL and LLNL alternatives only consider the incremental changes for operating the production facilities. The actual production footprint size of each alternative is almost identical; however, the production capacities vary between site alternatives. For example, base case, multiple-shift capacities at Y-12 and LANL are about 150 units, whereas at LLNL the equivalent production capability would be about 50 units. This creates significant differences in some of the data. 

Process Descriptions 

Uranium. The uranium process provides finished uranium parts and products. The operations are capable of all uranium handling and processing functions, from raw materials handling to finished parts manufacturing. In addition, uranium storage areas need to be provided for storage of in-process uranium materials and, at ORR only, for the HEU strategic reserve. In the event secondary and case fabrication is phased out at ORR and performed at LANL or LLNL, the storage of the HEU strategic reserve would be addressed at the weapons A/D site (i.e., Pantex or NTS). 

The production of uranium parts and products involves casting or wrought processing; metal- working; machining, inspection, and certification; chemical recovery; assembly, disassembly, and quality evaluation; and in-process storage. The products from casting or wrought processing are billets and cast parts that feed directly to machining and metalworking. Billets are cropped and cast parts are delugged before they are sent to the next operation. The input to casting consists of retired weapons parts, metal buttons from storage, and recycled scrap metal from metalworking and machining. A casting charge is made up and processed in a critically safe configuration in a vacuum induction furnace. Scrap metal and machine turnings are degreased, cleaned, and briquetted before direct recycle. 

Metalworking prepares a wrought product as feed for machining. Cropped billets from casting are preheated in a salt bath, rolled into a sheet, annealed in a salt bath, blanked, and pressed. The blanking operations are a major source of recycled metal for casting. Formed parts are cleaned, debrimmed, and machined. 

Both formed and cast blanks are machined to finished dimensions and inspected. Scrap metal and machine turnings are returned to casting for cleanup and reuse. Miscellaneous solids are sent to the chemical recovery systems for treatment to recycle the material back to metal buttons. Product inspections and certification is accomplished with coordinate measuring machines, optical gaging, high-energy x-ray radiography, ultrasonic and dye penetrant flaw-inspection methodology, plating thickness gaging, and mechanical properties testing. 

Uranium chemical recovery receives feed from virtually all areas in the process. The major feeds are residuals from casting, impure metal chips from machining, and a miscellaneous array of combustibles from all areas. The feeds are incinerated and processed in a head-end treatment consisting of acid dissolution, leaching, and feed preparation for solvent extraction. The feed solution is processed through primary extraction by which it is purified, concentrated by evaporation, and purified further by secondary extraction. The resulting solution is converted to oxide, then to uranium tetrafluoride, and then to uranium metal buttons. Secondary residues are returned to the head-end treatment. Finished metal is returned to casting for reuse. 

Assembly operations assemble piece parts into subassemblies using joining techniques such as welding, adhesive bonding, and mechanical joining. Disassembly takes retired weapons apart and recycles all materials of value. The quality evaluation function receives weapons from the stockpile for disassembly, evaluation, and lifecycle testing. Shipping containers for weapons parts and subassemblies are certified and refurbished as part of the A/D process. 

Uranium storage includes storage vaults for in-process uranium materials, which includes buttons and other scrap materials directly recycled, as well as semi-finished and finished components. The vaults at ORR are also for the strategic reserve, which includes assembled secondaries and HEU metal castings. 

Lithium. The lithium process provides finished lithium hydride and deuteride parts. Primary functional elements of this process include powder production and forming, finishing and inspection, and deuterium production. These systems are briefly described below. 

The lithium hydride and deuteride from storage, recycled weapons parts, and manufacturing scrap are broken, crushed, and ground to produce powder. The powder is loaded into molds and cold isostatically pressed to form solid blanks. 

The blanks are unloaded from the molds and placed into vacuum furnaces where they are outgassed by heating under vacuum. After cooling, the outgassed blanks are loaded into form-fitting bags, heated, and then warm pressed. After being warm pressed, the blanks are cooled to room temperature and removed from the bags. The fully dense machining blanks that result from forming operations are radiographed to detect any high-density inclusions. Powder production, mold loading, and radiography are all performed in dry glove boxes to minimize reaction of the lithium hydride and deuteride with moisture in the atmosphere. Mold unloading, furnace loading and unloading, and bag loading and unloading are all conducted in an inert glove box. The lithium hydride or deuteride is handled outside inert-atmosphere glove boxes only when it is sealed in a mold or bag. 

The blanks from forming operations are machined to final shapes and dimensions on lathes using single-point machining methods in finishing operations. Most machine dust is collected for direct recycle salvage operations. The finished part weight and dimensions are inspected using certified balances and contour measuring machines. All machining and inspection activities are conducted in dry glove boxes to minimize any reaction with moisture in the atmosphere. Certified parts receive a final vacuum outgassing treatment before final assembly. 

Deuterium is required for many of the products and will be stored for future use. Deuterium oxide, or heavy water, is electrolytically reduced. The resulting deuterium is compressed and stored for use. The compressed deuterium gas is used to reconvert the lithium metal to deuteride in the final step of wet chemistry if needed. 

Lithium wet chemistry can be used to pre-produce lithium hydride and deuteride to meet production requirements for many decades. The principal function of wet chemistry is to purify lithium hydride and deuteride by removing oxygen and other trace elements. The principal feeds to this system are retired weapon components from the disassembly operation, machine dust, powder, and killed parts from other operations. Purification is accomplished by transforming the lithium hydride and deuteride through a chemical dissolution process; then the solution is evaporated and crystallized. The crystals are then reduced to lithium metal and impurities are removed. The lithium metal is then reconverted to lithium hydride and deuteride by combining it with hydrogen or deuterium gas. The resulting lithium hydride and deuteride billet, sealed in a thin stainless-steel can, is transferred to lithium storage. 

The production of lithium hydride and deuteride components creates a considerable amount of scrap that must be recycled to recover the lithium and deuterium. Much of the machine dust, unacceptable formed parts, machined parts that fail inspection, and stockpile returned parts are directly recycled. Salvage operations typically process material that is too impure to be recycled. Salvage operations primarily involve washing and chemical recovery. Items that require washing include machining tools and fixtures, filters used throughout the processes, and sample bottles. Oil-soaked lithium hydride and deuteride blanks from the powder-forming operations are also prepared for storage. Solutions from the purification and wash operations, including mop and dike water streams, are neutralized, filtered, crystallized, and sent to storage or waste disposal. 

Long-term storage is required for chemicals and pre-produced lithium hydride and deuteride billets. Interim storage is to be provided for lithium hydride and deuteride components from disassembly or retired weapons and rejected components from forming and finishing operations. 

Special Materials. Special materials such as diallyl-phthalate are required to support the lithium processes. Diallyl-phthalate based molding compound is formed into near-net-shape blanks that are later machined to finished parts. The primary forming operation is compression or transfer molding, which is followed by a drying and final curing step. 

Nonnuclear. The nonnuclear process is responsible for producing certain weapon components composed of nonnuclear materials and for providing the uranium and lithium processes with specialized material and support services. Many types of materials are processed to provide a diverse product line consisting of both nonnuclear metal components and tooling and a variety of polymer-based items. The principal manufacturing technologies employed are hydroforming, hydrostatic forming, rolling, forging, heat treating, welding, machining, cold/hot isostatic pressing, grinding, winding, casting, plating, molding, and coating. 

The nonnuclear process handles several product streams, which are described briefly in the following paragraphs. 

Several types of urethane foams are required to be produced. The urethane components and blowing agents are pumped into molds and allowed to expand to fill the mold. After curing, the foam moldings are ejected and trimmed to final shape. 

Steel and aluminum are construction materials for both components and support tooling, making this a relatively high throughput product line. The usual fabrication route for both materials is rough machining, heat treatment, and finish machining. 

Operations to produce stainless steel cans consist of blanking, followed by hydroforming and hydrostatic forming with subsequent machining and heat treatment. Ultrasonic cleaning is required before heat treatment to ensure cleanliness for welding, which completes the assembly. 

Ceramic finished parts are finished from blanks or procured. Procured parts are inspected and certified prior to final assembly. 

Polyvinyl chloride is formed into bags and castings and also applied as a coating. Items to be coated are dipped into a tank of curable, plasticized polyvinyl chloride formulation, whereas castings are produced by transferring the polyvinyl chloride liquid into a mold. All items are heat cured.

A.3.2.1 Downsize at Oak Ridge Reservation

Y-12 has performed the secondary and case fabrication mission in the Complex for over 40 years. This mission includes the production of materials and components for thermonuclear weapons secondary assemblies and the associated functions such as depleted uranium for radiation cases and other miscellaneous materials for other applications. Figure A.3.2.1-1 shows the location of Y-12 at ORR. 

The Y-12 secondary and case fabrication mission requires approximately 30 ha (75 acres) of the existing 328-ha (811-acre) Y-12 site. This, unlike the LANL and LLNL alternatives, includes significant area for support facilities. There would be no new developed land outside the currently existing Y-12 boundary. Land for construction laydown and warehousing would be minimal and would use existing Y-12 developed areas; construction parking requirements, about 0.8 ha (2 acres), can be satisfied by existing unused parking facilities. 

The Y-12 complex consists of an array of production and support facilities. The physical configuration for the Y-12 secondary and case fabrication mission consists of five main production buildings, one shared production facility, and a number of office, utility, and changehouse facilities. 

During the past 12 years, major restoration projects (such as Production Capability Restoration, Utility System Restoration, and the Capability Assurance Program) have brought the infrastructure supporting this facility up to current standards and should allow the use of these facilities for up to an additional 40 years. Figure A.3.2.1-2 is a plot plan of Y-12 showing these main and shared facilities. 

The secondary and case fabrication mission would be located in the following Y-12 production buildings: 9996, 9212, 9215, 9201-5N, 9204-2E, 9204-2 (isostatic press), 9720-19, and 9998. The secondary and case fabrication mission footprint comprises 61,800 m 2 (665,000 ft 2 ) of total DP area including a production footprint of 21,840 m 2 (235,000 ft 2 ). The total proposed footprint includes all DP functions: production, storage, maintenance, dedicated utilities, and administration. Buildings 9204-2 and 9201-5W would be placed in cold standby to enable reactivation in the event of unforeseen additional capacity demands. Activation of these buildings would require separate NEPA evaluation. 

The following production buildings would be used to support the Stockpile Stewardship and Management Program. 

Building 9212 

Building 9998 

Building 9215 

Building 9996 

Building 9204-2 

Building 9201-5N 

Building 9201-5W 

Building 9720-19 

Building 9204-2E 

No new facilities are required at Y-12 to support the secondary and case fabrication mission. Table A.3.2.1-1 summarizes key facility data, such as plant functions, nuclear materials present, building square footage, number of floors in the building, and type of construction. 

Construction. Modification of Y-12 facilities to support the secondary and case fabrication mission would require 6 years to complete. The materials and resources that would be consumed during this period are summarized in table A.3.2.1-2. Emissions generated during construction are provided in table A.3.2.1-3. The principal sources of airborne emissions from construction are fugitive dust, construction activities, and exhaust from construction equipment and vehicles. Construction employment for the Y-12 Secondary and Case Fabrication Facility modification is shown in table A.3.2.1-4

Operations. The secondary and case fabrication mission processes require the following utilities during operations: electricity, diesel fuel, natural gas, coal, air (compressed, dehumidified, and breathing), water (demineralized, fire, potable, plant, and cooling tower), and steam. Table A.3.2.1-5 presents the estimated utilities consumed during surge operation of the Y-12 secondary and case fabrication facilities. Chemicals consumed during secondary and case fabrication surge operations are summarized in table A.3.2.1-6

Emissions. The contaminated and potentially contaminated zones within the plant facilities that handle uranium materials have high efficiency particulate air (HEPA) filtered ventilation systems that exhaust to the atmosphere. Some exhausts are provided with liquid scrubbing prior to HEPA filtration to remove chemical vapors such as nitric acid. The annual emissions for surge operation of the Y-12 secondary and case fabrication mission are shown in table A.3.2.1-7

Table A.3.2.1-1.-- Y-12 Plant Secondary and Case Fabrication Facility Data 

Building 

Number

Upgraded Uranium/Lithium Plant Function

Upgraded Uranium/Lithium Facility Usage

(percent)

Nuclear Materials Present

Total

Size

(m 2 )

Number of 

Floors

Type of Construction 1 

9103Communication/support 10  6,7803 B-1
9117Communication/support 10  1,8101 A-5
9119Administration/support 100  6,6604 B-5
9201-5NUranium/nonnuclear 85Uranium 7,4802 B-2
9204-2EUranium 85Uranium 14,050 3B-1
 Lithium 10Lithium     
 Maintenance/support 5      
9212 2  Uranium 40Uranium 28,930 3B-2
9215Uranium 90Uranium 14,590 3B-2
 Nonnuclear 10      
9401-3Steam plant support 10  3,1303 B-4
9404-2Compressed air/support 40  4301 B-2
9706-2Emergency Operations Center  20  2,0402 A-2
 Medical/support 20      
9710-2Fire station 10  1,7601 B-2
9710-3Security/support 60  3,8204 B-3
9711-5Cafeteria/support 10  5,3602 B-1
9723-31Changehouse/support 50  2,7102 B-3
9995Plant laboratory    7,8102 B-3
 Uranium 6Uranium     
 Lithium 3Lithium     
 Nonnuclear 1      
9996Uranium 100Uranium 3,1102 B-3
9998Uranium 70Uranium 12,740 2B-3
 Nonnuclear 20      

Table A.3.2.1-2.-- Y-12 Plant Secondary and Case Fabrication Construction Materials/Resources Requirements

Material/Resource

Total Consumption

Peak Demand 3 

Concrete (m3)100 
Electricity (MWh)2.7 0.2 MWe
Industrial gases 4 (m 3 ) 300  
Liquid petrochemicals (L)10,000  
Steel (t)20  
Water (L)2,000,000   

Table A.3.2.1-3.-- Y-12 Plant Secondary and Case Fabrication Construction Emissions 

Pollutant

Quantity

(t)

Carbon monoxide2.4
Nitrogen oxides0.8
Particulate matter0.6
Sulfur dioxide0.1
Total suspended particles1.0
Volatile organic compounds1.2

OR MMES 1996j

 

Table A.3.2.1-4.-- Y-12 Plant Secondary and Case Fabrication Construction Workers

Employees

97

98

99

00

01

02

Total 5 

Craftworkers          
Carpenter0.40.4 0.40.40.4 02
Concrete mason0.20.2 0.20.20.2 01
Electrician11 110.5 0.55
Iron worker22 222 212
Laborer11 211 17
Millwright 0.5 0.50.50.5  2
Operator0.50.5 0.50.50.5 0.53
Other craftworkers0.2 0.20.20.2 0.2 1
Pipe fitter0.50.5 0.50.50.5 0.53
Sheet metal worker0.4 0.40.40.4 0.4 2
Sprinkler fitter        0
Teamster0.30.3 0.30.40.4 0.32
Total Craftworkers6.5 7.08.07.1 6.64.840 
Construction management and support staff 5.25.66.4 5.75.33.8 32
Total Employment 11.7 12.614.412.8 11.98.672 

Table A.3.2.1-5.-- Y-12 Plant Secondary and Case Fabrication Surge Operation Annual Utility Requirements

Utility

Consumption

Peak Demand 6 

Coal (t)500  
Diesel fuel (L)250,000  
Electricity118,000 MWh 19.0 MWe
Natural gas 7 (m 3 ) 17,000,000 
Raw water (L)1,510,000,000  

Table A.3.2.1-6.-- Y-12 Plant Secondary and Case Fabrication Surge Operation Annual Chemical Requirements

Chemical

Quantity 
(kg)

Solid Chemicals  
Aluminum trihydride3,000
Barium nitrate15
Borax15
Calcium hydroxide30,000
Calcium nitrate150
Calcium oxide150
Curing agent4
Diatomaceous earth2,500
Epoxy resin10
Erbium oxide75
Ferric sulfate7,500
Graphite2,000
Lithium carbonate1,200
Magnesium sulfate100
Methylene diphenyl diisocyanate100
Nickel compounds75
Polycure75
Potassium carbonate3,000
PVC plastisol1,500
Silicon carbide40
Sodium bicarbonate75
Sodium carbonate450
Sodium molybdate dihydrate5
Sodium nitrate1,500
Sodium potassium3
Trisodium phosphate250
Tungsten carbide1
Yttria150
Zirconium oxide180
Liquid Chemicals  
Acetic acid15
Acetone8
Acetonitrile150
Anisol200
Corrosion inhibitor800
Diamond paste1
Diesel fuel75,000
Ethanol1,000
Gasoline110,000
Hydraulic oil3,000
Hydrogen peroxide750
M-pyrol50
Methanol2,500
Micro/oakite detergent12
Mineral oil1,500
Mold release7.5
Nitric acid1,000
Nitrogen tetroxide150
Oxalic acid2
Petroleum oils (lubricants)1,500
Potassium chloride15
Propylene glycol150
Pump oil3
PVC primer2
Solvent 140750
Toluene 2,4-diisocyanate100
1,1,1-Trichloroethane800
Gaseous Chemicals  
Ammonia, anhydrous7.5 
Argon1,400,000 
Carbon dioxide30,000 
Chlorine75 
Freon or equal (cleaning)750 
Helium6,000 
Hydrogen1,500 
Nitrogen5,000,000 
Oxygen50,000 
Note: PVC- polyvinyl chloride. Source: OR MMES 1996j; ORR 1995a:4 . 



Employment. Y-12 generally operates with one shift per day, 5 days per week, except for some utility systems and security functions that operate continuously. Surge capacity would be accommodated by operating multiple shifts. The employment during surge operation for the secondary and case fabrication mission is summarized in table A.3.2.1-8. The data presented includes employees from the management and operating contractor, support organizations, and DOE. 

Table A.3.2.1-7.-- Y-12 Plant Secondary and Case Fabrication Surge Operation Annual Emissions 

Pollutant

Quantity 

(t)

Carbon monoxide7.4
Chlorine0.15
Hydrogen chloride4.8
Methyl alcohol14
Nitric acid7.1
Nitrogen oxides195
Ozone0.07
Particulate matter0.5
Pressing lubricant0.3
Sulfuric acid1.8
Sulfur dioxide80
Total suspended particles10
Volatile organic compounds1.2
Radiological Isotope 

Estimated Release 

Uranium-235 (microcuries)420
Uranium-238 (microcuries)1,490

OR MMES 1996j; ORR 1995a:4. 

Approximately 20 percent of the dosimeter badged population at Y-12 routinely work inside the radiological area (uranium handling areas). Based on current design definition, 20 percent is also assumed for the Y-12 secondary and case fabrication mission. Therefore, it is estimated that 174 of the badged employees would be at risk of radiological exposure as shown in table A.3.2.1-8. In addition, on a nonroutine basis, a small fraction of badged visitors may enter the radiological area. 

Table A.3.2.1-8.-- Y-12 Plant Secondary and Case Fabrication Surge Operation Workers 

Labor Category

Number of Employees

Risk of Radiological Exposure

Craftworkers13161
Laborers8--
Officials and managers88 7
Office and clerical95 --
Operatives9343
Professionals28435
Service workers584--
Technicians9328

Total Employees 

1,376 174

OR MMES 1996j; ORR 1995a:4. 

Waste Management. The solid and liquid nonhazardous wastes generated during modification activities would include concrete and steel construction waste materials and sanitary wastewater. The steel waste would be recycled as scrap material before completing construction. The remaining nonhazardous wastes generated during construction would be disposed of by the construction contractor. Uncontaminated wastewater would be managed per site practice. Wood, paper, and metal wastes would be shipped offsite to a commercial contractor for recycling. Hazardous wastes would be packaged in DOT-approved containers and shipped offsite to commercial RCRA-permitted treatment, storage, and disposal facilities. A small amount of solid LLW consisting of contaminated steel and concrete would be generated. This waste would be placed in an appropriate container and shipped to an approved LLW disposal facility. 

The project design considers and incorporates waste minimization and pollution prevention. Production processes would be configured with minimization of waste production given high priority. Future D&D considerations have also been incorporated into the design. 

Table A.3.2.1-9 presents the estimated annual waste volumes from the secondary and case fabrication facilities during modifications and surge operations. Solid and liquid waste streams are routed to the waste management system. Figures A.3.2.1-3 through A.3.2.1-6 [figure A.3.2.1-4] [figure A.3.2.1-5] depict the waste management system. Solid wastes would be characterized and segregated into low-level, hazardous, and mixed wastes, then treated to a form suitable for disposal or storage within the facility. Liquid wastes would be treated onsite to reduce hazardous/toxic and radioactive elements before discharge or transport. All fire-sprinkler water discharged in process areas would be contained and treated as process wastewater, when required. 

Table A.3.2.1-9.-- Y-12 Plant Secondary and Case Fabrication Waste Volumes

Category

Annual Average Volume Generated from Construction (m 3 )

Annual Volume Generated from Surge Operations (m 3 )

Annual Volume Effluent from
Surge Operations (m 3 )

Low-Level     
LiquidNone320 None
Solid81,120 8  570 9 
Mixed Low-Level     
LiquidNone3,400 3,400
Solid192 10  92
Hazardous     
LiquidNoneIncluded in mixed Included in mixed
Solid2Included in mixed Included in mixed
Nonhazardous (Sanitary)     
Liquid27320,000 319,400 11 
Solid30 12  13,500 13  7,670 14 
Nonhazardous (Other)     
LiquidIncluded in sanitary Included in sanitaryIncluded in sanitary
Solid210,000 15  Included in sanitary

Spent Nuclear Fuel. The Secondary and Case Fabrication Facility would not generate any spent nuclear fuel. 

Transuranic Waste. The Secondary and Case Fabrication Facility would not generate any TRU wastes. 

Low-Level Waste. LLW would be generated by operation of the Secondary and Case Fabrication Facility and would consist primarily of depleted uranium oxide in drums and contaminated scrap metal, air filters, and HEPA filters. Approximately 10 percent of all LLW generated would currently be suitable for disposal onsite. The remaining waste would be packaged for offsite treatment and disposal at the waste feed preparation facility and stored at K-25, pending disposal at an approved disposal facility. Scrap metal would be sent offsite for smelting into shielding blocks for DOE use. 

Mixed Low-Level Waste. Mixed LLW would be generated from operation of the Secondary and Case Fabrication Facility and would consist primarily of ash and sludge immobilized in grout, compacted gloves, and wipes. Mixed LLW would be collected in DOT-approved containers and sent to an onsite hazardous waste accumulation area. Waste suitable for incineration would be sent to the K-25 TSCA incinerator. After compaction, if appropriate, the remaining solid wastes would be packaged and stored onsite awaiting disposal by an offsite commercial vendor. 

Hazardous Waste. These materials are included in the mixed LLW. 

Nonhazardous (Sanitary) Waste. Sewage wastewater would be discharged directly to the Oak Ridge Municipal Wastewater Treatment System sewer system. Process wastewater would be treated in the sanitary wastewater treatment facilities and discharged through permitted NPDES outfalls. Sludge would be stored onsite, pending treatment by a commercial vendor. Nonhazardous solid wastes including small amounts of classified nonhazardous waste would be generated from operation of the Secondary and Case Fabrication Facility and disposed of in a State of Tennessee permitted Class II landfill. 

Nonhazardous (Other) Waste. Nonrecyclable (other) wastes would be disposed of in a permitted landfill or discharged through permitted NPDES outfalls. 

A.3.2.2 Relocate to Los Alamos National Laboratory

LANL secondary and case fabrication facilities would include all of the functional operations required to physically and chemically process, machine, inspect, assemble, certify, and disassemble secondary materials to produce canned subassemblies and radiation case components for the nuclear weapons physics package. 

The secondary and case fabrication facilities would occupy 21,739 m2 (234,000 ft2) of floor space inside existing structures within their current footprint of 1.1 ha (2.7 acres). Additional land area for the construction of new buildings would not be required. A nominal area would be required for equipment staging, material laydown, and parking during the modifications of these facilities. 

Facility Description. Secondary and case fabrication would utilize existing facilities within the boundaries of TAs -3, -8, -50, -54, and -55 (figure A.3.2.2-1). Facilities within each of these technical areas include the TA-3 Sigma Complex (SM-35, SM-66, and SM-141), the TA-3 Chemistry and Metallurgy Research building (SM-29), the TA-3 main machine shop (SM-39 and SM-102), the TA-8 Nondestructive Evaluation Facility (Buildings 22 and 23), the TA-55 Nuclear Material Storage Facility for overflow capacity, the TA-50 Liquid Radioactive Waste Treatment Facility, and the TA-54 Solid Radioactive Waste Treatment Area. 

The flow of fissile material would be contained within the Chemistry and Metallurgy Research building (SM-29). Manufacturing operations would take their feeds from both incoming stockpile returns and the chemical recovery process. Components from manufacturing would be sent back out for assembly. Low-equity waste (graphite, booties, and machining fluids) would be sent back to waste management for processing, storage, and disposal. Recoverable quantities of fissile material would be reprocessed in chemical recovery and returned as feed stock to manufacturing. 

Figure A.3.2.2-2 shows the major structures located in TA-3. The buildings shown on this plot plan for use in stockpile stewardship and management operations are SM-29, SM-35, SM-39, SM-66, SM-102, and SM-141. Modifications are required for the following facilities: 

Table A.3.2.2-1 summarizes key facility data for the building and support structures to be utilized in secondary and case fabrication. 

The Chemistry and Metallurgy Research building is a large reinforced concrete building with a basement, a first floor, and an attic floor. This building has been classified as a Performance Category PC-3 Nuclear Facility (per DOE-STD-3009-94). The administration wing and Wing 1 contain second-floor office areas. The plan of the building is centered on a spinal corridor oriented in a north-south direction with an administration wing and seven laboratory wings (Wings 1, 2, 3, 4, 5, 7, and 9) that extend from the corridor. Wings 2, 3, 4, 5, and 7 have equipment/change rooms located at the front of each wing and filter towers located at the end of the wings, which house the filter plenum and other large mechanical equipment for the exhaust ventilation system. The building also contains a waste assay facility located at the loading dock between Wings 1 and 4 and a Category I special nuclear material vault. The Chemistry and Metallurgy Research building replaced the World War II "D" building and was designed to house analytical chemistry facilities, plutonium metallurgy, uranium chemistry, engineering design and drafting, electronics, and other support functions. At the time it was built, the Chemistry and Metallurgy Research building represented the state-of-the-art instrumentation and safety controls for a modern chemistry laboratory. 

Table A.3.2.2-1.-- Los Alamos National Laboratory Secondary and Case Fabrication Facility Data

Building

Footprint

(m2)

Number 
of 
Levels

 

Special Materials

 

Construction Type

 

SM-29 Chemistry and Metallurgy Research 51,0973Special nuclear materials Concrete post and beam with concrete masonry unit in-fill walls
SM-66 Sigma15,7943 NAConcrete post and beam with concrete masonry unit in-fill walls
SM-39 Nonnuclear Shops14,202 3NAConcrete post and beam with concrete masonry unit in-fill walls
SM-102 Uranium Shops2,090 3NAConcrete post and beam with concrete masonry unit in-fill walls
SM-141 Rolling Mill1,858 2NAConcrete post and beam with concrete masonry unit in-fill walls
SM-35 Press9292 NAConcrete foundation with steel pillars and sheet metal walls
SM-67 Guard Station Sigma22.9    
SM-127 Cooling Tower138    
SM-145 Switchgear Station39    
SM-147 Air Plenum and Fan 15.2    
SM-154 Chemistry and Metallurgy Research Cooling Tower 37.2    
SM-159 Forming14.9    
SM-161 Magazine1.5    
SM-169 Warehouse581    
SM-187 Cooling Tower37.2    
SM-317 Graphite Flour Storage140.5    
SM-451 Micro Machining160    
TA-8-22 Nondestructive Evaluation Lab843    

TA-8-23 Nondestructive Evaluation Support

316    

NA - not applicable.

LANL 1995e.

     

The Sigma Complex comprises three main processing buildings located in TA-3 just east of the Chemistry and Metallurgy Research building. The fenced area encompassing the Sigma Facility contains a total of 16 buildings. The three buildings designated as SM-66, SM-141, and SM-35 contain the majority of laboratory space. Other structures house utilities, support functions, and storage areas. The Sigma Complex has been classified as a low-hazard chemical (PC-1), nonnuclear facility. 

The Press building (SM-35) is the oldest building in this complex. Construction was completed in 1953. The building was originally designed to house the 4,536-t (5,000-ton) press for the Materials Technology Group. Building construction consists of a concrete foundation and supporting steel pillars with insulated double sheet metal walls outside. Inside walls (separating various work areas and offices) are similar or made of concrete block. 

The Rolling Mill building (SM-141) has reinforced concrete foundations, floors, support columns, and beams with concrete block exterior walls. Interior walls separating various work areas and offices are made of concrete block and/or metal studs with gypsum board. The roof is built of tar and gravel over rigid insulation and is supported by steel joists. The building was designed to house areas for powder metallurgy and fabrication. Today the Rolling Mill building continues to house these activities in addition to work areas for ceramics research, beryllium technology, and development and rapid solidification research. 

The Sigma building (SM-66) was constructed in 1959 and was originally designed to house activities in physical metallurgy, ceramics, powder metallurgy, plastics, a metal foundry, electrochemistry, fabrication, and other support functions. Today the Sigma building continues to house all these functions except plastics. The building is built on a reinforced concrete foundation using reinforced concrete post and beam construction techniques. The exterior walls are constructed of concrete block fill between the supporting posts and beams. The mezzanine spaces are constructed of supported metal decking. Interior walls separating various work areas and offices are also concrete block or metal studs and gypsum board. The roof is built of tar and gravel over rigid insulation and metal decking supported by steel joists. The building has a basement, a first floor, and a small second floor. The plan of the building is on a spinal corridor oriented in a north-south direction. SM-66 has 11 major work areas that extend from the corridor. 

Building SM-102 is connected to the Main Shops building, SM-39, by a 38-m (125-ft) long corridor. Constructed in the late 1950s, it originally housed a foundry, a heat-treating operation, a graphite machining shop, and a radioactive materials machine shop. Since that time, the northeast corner of the building, which provided programmatic support to the Rover Project, has been decommissioned and now is dedicated to the support of Engineering, Sciences, and Applications division operations. Currently, the southern half of the building is occupied primarily by Shop 13, the uranium and lithium machine shops. The building is constructed of cinder block and has a concrete floor. Shop 13 contains machines that are used for machining operations on uranium. The majority of the building houses pyrophoric, toxic, and radioactive material machining and a dimensional inspection area. SM-102 has been classified as a low-hazard chemical (PC-1), nonnuclear facility. 

Building SM-39 is of concrete and cinder block construction. The main bay is aligned from north to south and is 183 m (600 ft) in length by 37 m (120 ft) in width. Three wings extend eastward from the north and south ends of the bay, as well as the middle of the main bay. The south main (high) bay section, the middle wing, and the south wing contain metal and machining shops owned by the Mechanical Fabrication Group. SM-39 has been classified as a low-hazard chemical (PC-1), nonnuclear facility. 

The north wing contains offices occupied by the Materials Technology Polymers & Coatings Group (MST-7) and the Standard and Calibration Group (ESH-9). It also contains Mechanical Fabrication Group beryllium machining and inspection, a glass shop operated by MST-7, and a Standards and Calibration Laboratory operated by ESH-9. Three transportable equipment storage trailers are located on the south side of the north wing. 

Construction. Modification to the LANL facilities to perform the stockpile management secondary and case fabrication mission would require approximately 7 years for design, construction, mission transfer, and operational startup. With conceptual design beginning in 1997, operational startup could commence in 2004. The materials and resources consumed during modification activities are provided in table A.3.2.2-2

Emissions generated during modification activities are provided in table A.3.2.2-3. The principal sources of airborne emissions during modification are fugitive dust, construction debris, and exhaust from construction equipment and vehicles. 

Table A.3.2.2-2.-- Los Alamos National Laboratory Secondary and Case Fabrication Construction Materials/Resources Requirements

Material/Resource

Total Consumption

Peak Demand 16 

Concrete (m 3 )245  
Electricity4,130 MWh 0.75 MWe

Industrial gases 17 (m 3 )

11,500 
Liquid fuel (L)22,700  
Steel (t)54 
Water (L)4,160,000 

Table A.3.2.2-3.-- Los Alamos National Laboratory Secondary and Case Fabrication Construction Emissions

Pollutant

Quantity
(t)

Carbon monoxide<1 18 

Lead

0
Nitrogen dioxide<1 18 
Particulate matter<1 18 
Sulfur dioxide<118
Volatile organic compounds0

Employment needs during the modification phase are presented in table A.3.2.2-4

Operation. The secondary and case fabrication processes require the following utilities during operation: electricity, natural gas, diesel fuel, air, water, and steam. Table A.3.2.2-5 presents a listing of the utilities consumed during Secondary and Case Fabrication Facility surge operations. Chemicals consumed during operation are summarized in table A.3.2.2-6

The annual emissions from surge operation required in the Secondary and Case Fabrication Facility are based on historical emissions and amounts of materials to be processed as shown in table A.3.2.2-7

Employment. The employment needs in support of secondary and case fabrication surge operation activities at LANL are summarized in table A.3.2.2-8

Table A.3.2.2-4.-- Los Alamos National Laboratory Secondary and Case Fabrication Construction Workers by Year

Labor Category

Year 1

Year 2

Year 3

Year 4

Total

Total craftworkers34 454545 169
Construction management and support staff 61010 1036

Total Employment 

  40  55  55   55  205

LANL 1995e.

     

Table A.3.2.2-5.-- Los Alamos National Laboratory Secondary and Case Fabrication Surge Operation Annual Utility Requirements

Utility

Consumption

Peak Demand 19 

Diesel fuel (L)100,000  
Electricity36,000 MWh 5 MWe
Natural gas 20 (m 3 ) 0 

Water (L)

55,000,000  

Table A.3.2.2-6.-- Los Alamos National Laboratory Secondary and Case Fabrication 
Surge Operation Annual Chemical Requirements

Chemical

Quantity
(kg)

Solid Chemicals  
Aluminum nitrate75
Aluminum trihydride3,000
Barium nitrate15
Borax15
Calcium hydroxide30,000
Calcium nitrate150
Curing agent4
Epoxy resin10
Ferric sulfate7,500
Graphite2,000
Lithium chloride6,000
Magnesium sulfate100
Methylene diphenyl diisocyanate100
Nickel compounds75
Polycure75
Potassium carbonate3,000
PVC plastisol1,500
Silicon carbide40
Sodium bicarbonate75
Sodium carbonate450
Sodium molybdate dihydrate5
Sodium nitrate1,500
Trisodium phosphate250
Tungsten carbide1
Yttria300
Liquid Chemicals  
Acetic acid15
Acetone20
Acetonitrile150
Anisol200
Corrosion inhibitor800
Diamond paste1
Dibutyl carbitol1,000
Ethanol1,000
Gasoline and diesel100,000
Hydraulic oil3,000
Hydrogen peroxide750
Kerosene, high grade150
M-pyrol50
Methanol2,500
Micro/oakite detergent12
Mineral oil1,500
Mold release7.5
Nitric acid1,000
Nitrogen tetroxide150
Oxalic acid2
Petroleum oils (lubricants)1,500
Potassium chloride15
Propylene glycol150
Pump oil3
PVC primer2
Solvent 140750
Toluene 2,4 diisocyanate100
Gaseous Chemicals  
Ammonia, anhydrous7.5 
Argon1,000,000 
Carbon dioxide10,000 
Chlorine75 
Freon or equal (cleaning)750 
Helium6,000 
Hydrogen1,500 
Nitrogen500,000 
Oxygen50,000 
Note: PVC- polyvinyl chloride. Source: LANL 1995b:4; LANL 1996e:1.

Table A.3.2.2-7.-- Los Alamos National Laboratory Secondary and Case Fabrication 
Surge Operation Annual Emissions

Pollutant

Quantity
(t)

Carbon monoxide4.5
Lead0.1
Nitrogen dioxide117
Particulate matter0.3
Sulfur dioxide48
Volatile organic compounds0.6
Radiological Isotope Estimated Release 
Uranium 235 (microcuries)486
Uranium 238 (microcuries)1776

LANL 1995b:4.

Table A.3.2.2-8.-- Los Alamos National Laboratory Secondary and Case Fabrication 
Surge Operation Workers

Labor Category

Number of Employees

Employees at Risk of Radiological Exposure

Office and clerical26 0
Officials and managers34 4
Professionals3713
Service workers24461
Technicians18273

Total Employees 

523 21 151

Nearly all of the personnel performing operations in the secondary fabrication facilities would be dosimeter-badged. As shown in table A.3.2.2-8, it is estimated that approximately 151 workers would be at risk of radiological exposure. In addition, a small fraction of badged visitors may nonroutinely enter radiological areas. 

Waste Management. Wastes generated during secondary and case fabrication operations include radioactive, mixed, hazardous, and nonhazardous byproducts. Secondary and case fabrication operations would not generate any high-level or TRU wastes. Low-level radioactive waste would consist primarily of depleted uranium oxide chips, contaminated scrap metal, and filter media. Mixed and hazardous wastes would consist of ash, sludges, filters, rags, and wipes. Liquid radioactive and inorganic chemical wastes that meet the LANL waste acceptance criteria are sent either by truck or industrial drain to be processed at TA-50, Building 1. Mixed wastes are currently stored at TA-54; liquids in Area L and solids in Area G. Hazardous and organic chemical (RCRA) wastes are packaged and shipped to TA-54, Area G, for interim storage and subsequently shipped offsite. Nonhazardous solid waste is collected in dumpsters and taken to the landfill operated by Los Alamos County. Sanitary liquids are disposed of by either sanitary drain or permitted outfall. Sanitary process and support liquids are sent by drain to the sanitary wastewater treatment plant, TA-46, and treated similarly to municipal sewage. Table A.3.2.2-9 provides an estimate of the annual quantities of these waste categories for Secondary and Case Fabrication Facility surge operation. 

Table A.3.2.2-9.-- Los Alamos National Laboratory Secondary and Case Fabrication 
Waste Volumes

Category

Annual Average 
Volume Generated 
from Construction
(m 3 )

Annual Volume 

Generated from 

Surge Operations
(m 3 )

Annual Volume 

Effluent from 

Surge Operations
(m 3 )

Low-Level     
LiquidNone192 None
Solid134690 349 22 
Mixed Low-Level     
LiquidNone30 30
Solid10108 108
Hazardous     
LiquidNone60 60
Solid37216 216
Nonhazardous (Sanitary)     
Liquid89020,240 20,370
Solid1201,160 639 23 
Nonhazardous (Other)     
LiquidIncluded in sanitary NoneNone
Solid10 24  3,0003,000

A.3.2.3 Relocate to Lawrence Livermore National Laboratory 

The LLNL secondary and case fabrication facilities would be housed within existing buildings at the Livermore Site (figure A.3.2.3-1). All of the structures required to house the secondary and case fabrication functions are in place; finalizing the capability would require installing some new equipment, moving existing equipment to other locations, and modifying some facilities to meet production requirements. A new structure, a 167-m2 (1800-ft2) steel framed, Butler-type building would be required to provide covered space within the Superblock protected area in which to house the enriched uranium inventory. At the Livermore Site, the existing security system for the fenced Superblock could be used with minor modifications to include Building 239, the radiographic facility for enriched uranium fabrication, assembly, disassembly, storage, and surveillance operations. 

Manufacturing and assembly of the canned secondary assemblies would take place in the buildings indicated on the Livermore Site plan, figure A.3.2.3-2. The overall site occupies approximately 332 ha (821 acres) and is surrounded by security fencing. The individual facilities to be used for secondary and case fabrication are within protected areas, limited areas, or exclusion areas as required for security and safeguards. Support facilities are located both inside and outside the security areas but inside the overall site perimeter fence, which is controlled at the entrances to the perimeter fenced area. The required facilities comprise approximately 19,500 m2 (210,000 ft2) and cover approximately 2 ha (5 acres). The Livermore Site has sufficient yard area and warehousing space to accommodate required laydown areas for receipt and staging of equipment and construction materials. In addition, parking for construction workers is available onsite. 

Facility Description. Uranium parts are fabricated within a high-security, fenced area of the Livermore Site Superblock. Building 332 would house casting, machining, chemical recovery, destructive testing, nondestructive testing, dimensional inspection, storage, and A/D/surveillance operations. LLNL would use Building 334 as an additional site for A/D/surveillance operations and for metalworking of uranium parts. 

The uranium processing facility is divided into three heating ventilation and air conditioning zones for radioactive contamination confinement. Zone 1 comprises areas where radioactive materials are handled and processed and includes enriched uranium receiving, processing, and storage areas. Zone 2 consists of areas where there is normally no radioactive contamination, but where there is the possibility of contamination. This zone includes the rooms containing glove boxes, process operating areas, and service corridors surrounding Zone 1 areas. Building 332 is a reinforced-concrete structure meeting the requirements of DOE 430.1, Life-Cycle Asset Management. The existing fire protection; radiation monitoring; heating, ventilation, and air conditioning; and emergency power facilities in Building 332 would be used. Building 239 would be used for radiography. Other buildings used in enriched uranium operations would include Building 177 for mass spectroscopy and Buildings 222, 235, and 251. These buildings are existing facilities that are adequate for this mission, and only minor modifications and upgrades would be needed. 

As in the uranium parts manufacture, Building 239 is used for radiography, Building 177 for mass spectroscopy, and Buildings 222 and 251 for chemical laboratory analysis. The existing facilities in Building 235 are used for chemical laboratory analysis and nondestructive testing. Additional non-destructive testing functions take place in Building 327. Building 322 is used for some uranium part plating operations. The existing facilities in Buildings 322 and 327 are adequate for this mission. All of these facilities have been reviewed and approved for adequacy of building construction in accordance with applicable design codes and standards for the planned mission to be performed. 

The special materials fabrication operations are performed in Buildings 231 and 241. Mass spectroscopy will be done in the existing facilities in Building 177, and chemical laboratory analysis in Buildings 222 and 235. Dimensional inspection is done in Building 321. Special materials would be fabricated in existing facilities in Building 231, with finishing operations to take place in Building 241. Again, all of these facilities have been reviewed and, with the exception of Building 241, approved for adequacy of building construction in accordance with applicable design codes and standards for the planned mission to be performed. Building 241 would require some minor, additional seismic retrofits before operations could commence. 

The nonnuclear component fabrication capabilities would be housed in the extended Building 321 area complex at the Livermore Site. This includes the major Buildings 321 (with Wings A, B, C), 327, 329, and 322. Mechanical specimen testing would be performed in Building 231. 

Table A.3.2.3-1 summarizes key facility data for the buildings and support structure to be utilized in secondary and case fabrication. While table A.3.2.3-1 summarizes all the facilities that are proposed for the canned secondary assemblies mission at LLNL, many of the facilities are used only for sample tests and are existing facilities that would be used as is and shared with other LLNL programs. Buildings 177, 222, 235, 251, 322, 327, and 329 fit into this category. The remaining facilities are discussed because they are the main processing facilities for the canned secondary assemblies mission. 

Table A.3.2.3-1.-- Lawrence Livermore National Laboratory Secondary and Case Fabrication Facility Data 

Building Name

Footprint
(m2)

Number
of Levels

Special
Materials

Construction Type

B-1757341 NoneReinforced concrete
B-177281 SNMSteel frame
B-2221131 SNMSteel frame
B-2311,6611 NoneSteel frame
B-2351402 SNMSteel frame
B-239, Radiography136 2 + basementSNMReinforced concrete
B-2416201 NoneSteel frame
B-251191 SNMSteel frame
B-32113,9452 NoneSteel frame
B-3221491 NoneSteel frame
B-3271431 NoneSteel frame
B-3294841 NoneSteel frame
B-3327382 SNMReinforced concrete
B-3344383 SNMReinforced concrete
New, Butler storage building167 1SNMSteel frame

SNM - special nuclear materials.

LLNL 1995e.

Construction. Modification to the Livermore Site facilities, as discussed above, to perform the secondary and case fabrication mission would require approximately 3 years based on a fiscal year 1998 start date, with the first production unit scheduled for the beginning of 2004. To meet this milestone, facilities would have to be in place several years before that date to provide for certification of equipment and processes and for training and certification of personnel. It is anticipated that facilities would be required to be in place for this activity no later than 2001. 

The materials and resources consumed during the modification phase are provided in table A.3.2.3-2. Information is based on a 3-year construction schedule. 

Table A.3.2.3-2.-- Lawrence Livermore National Laboratory Secondary and Case Fabrication Construction Materials/Resources Requirements

Material/
Resource

Total Consumption

Peak
Demand

Concrete (m3)612 
Electricity3,500 MWh 400 kW 25 
Gasoline, diesel fuel, and lube oil (L) 908,000 
Industrial gases 26 (m3) 142 
Steel (t)73 
Water (L)8,710,000 

Estimated emissions generated during modification activities for the secondary and case fabrication mission at LLNL are provided in table A.3.2.3-3. The principal sources of airborne emissions during facility modification would be fugitive dust, construction debris, and exhaust from construction equipment and vehicles. The peak year is defined as the year when modification activities would be the highest and equipment is anticipated to be arriving for installation. 

Table A.3.2.3-3.-- Lawrence Livermore National Laboratory Secondary and Case Fabrication Construction Emissions 

Pollutant

Quantity 
(t)

Carbon monoxide635
Oxides of nitrogen63.5

Particulate matter

544
Sulfur dioxide5.44
Volatile organic compound6.53

LLNL 1995e.

Employment needs during the modification period are presented in table A.3.2.3-4. The modification activities would include some site work on the secondary fence enclosure of Building 239; seismic upgrades to Buildings 231 and 242; upgrades to building utilities such as electrical distribution systems, heating, ventilation and air conditioning, and security systems; and installation and checkout of equipment. 

Table A.3.2.3-4.-- Lawrence Livermore National Laboratory Secondary and Case Fabrication Construction Workers

Employees

Year 1

Year 2 

Year 3

Total

Construction management and support staff 151510 40
Craftworkers115115 60290

Total Employment 

13013070 330

LLNL 1995e.

 

During modification activities, some support personnel and crafts would be at risk of radiological exposure. Approximately 20 personnel involved in decontamination of the 5 rooms in Building 332 would be at risk during the first year of construction. However, since the building is a certified plutonium handling facility, all construction personnel working in this building during the modification phase would be at some risk of radiological exposure. 

Operations. The secondary and case fabrication processes would require consumable materials and resources to maintain facility operations. Annual utility consumption for surge operations secondary and case fabrication at the Livermore Site is presented in table A.3.2.3-5

Table A.3.2.3-5.-- Lawrence Livermore National Laboratory Secondary and Case Fabrication Surge Operation Annual Utility Requirements

Utility

Consumption

Peak Demand 27 

Electricity15,000 MWh 2 MWe
Liquid fuel (L)85,200  
Natural gas 28 (m3) 566,000 

Raw water (L)

194,000,000  

Table A.3.2.3-6 lists the estimated annual chemicals consumed during surge operation of the secondary and case fabrication mission at LLNL. 

Table A.3.2.3-6.-- Lawrence Livermore National Laboratory Secondary and Case Fabrication Mission Surge Operation Annual Chemical Requirements 

Chemical

Quantity 
(kg)

Solid Chemicals
Aluminum trihydride875
Barium nitrate4
Borax4
Calcium hydroxide8,730
Calcium nitrate45
Calcium oxide45
Curing agent1
Diatomaceous earth730
Epoxy resin3
Erbium oxide25
Ferric sulfate2,200
Graphite590
Lithium carbonate350
Magnesium sulfate30
Methylene diphenyl diisocyanate30
Nickel compounds25
Polycure25
Potassium carbonate875
PVC plastisol450
Silicon carbide15
Sodium bicarbonate25
Sodium carbonate135
Sodium molybdate dihydrate1
Sodium nitrate440
Sodium potassium1
Trisodium phosphate75
Tungsten carbide0.3
Yttria45
Zirconium oxide55
Liquid Chemicals  
Acetic acid4
Acetone2
Acetonitrile45
Anisol60
Corrosion inhibitor240
Diamond paste0.3
Diesel fuel21,850
Ethanol300
Gasoline32,000
Hydraulic oil875
Hydrogen peroxide220
M-pyrol15
Methanol730
Micro/oakite detergent3
Mineral oil440
Mold release2
Nitric acid300
Nitrogen tetroxide45
Oxalic acid0.1
Petroleum oils (lubricants)440
Potassium chloride4
Propylene glycol45
Pump oil1
PVC primer1
Solvent 140220
Toluene 2,4-diisocyanate30
1,1,1-Trichloroethane235
Gaseous Chemicals  
Ammonia, anhydrous2 
Argon407,300 
Carbon dioxide8,750 
Chlorine25 
Freon or equal (cleaning)220 
Helium1,750 
Hydrogen440 
Nitrogen1,450,000 
Oxygen14,550 
Note: PVC- polyvinyl chloride. 

LLNL 1995e; LLNL 1995i:3.

The estimated annual emissions from surge operation of the Secondary and Case Fabrication Facility are based on historical emissions and amounts of materials to be processed and are shown in table A.3.2.3-7

Table A.3.2.3-7.-- Lawrence Livermore National Laboratory Secondary and Case Fabrication Surge Operation
Annual Emissions

Pollutant

Quantity
(t)

Carbon dioxide3,100
Carbon monoxide1.0
Chloride1.6
Chlorine0.05
Methyl alcohol4.5
Nitric acid2.3
Nitrogen dioxide1.9
Ozone0.03
Particulate matter 0.1
Pressing lubricant0.1
Sulfur dioxide0.02
Sulfuric acid0.6
Total suspended particulates3.2
Volatile organic compounds0
Water vapor1,040
Radiological Isotope Estimated Release 
Uranium-235 (microcuries)135
Uranium-238 (microcuries)480

LLNL 1995e; LLNL 1995i:3.

Employment. The additional employment needs in support of secondary fabrication surge activities at LLNL are summarized in table A.3.2.3-8

Approximately 250 (33 percent) badged employees would work inside radiological areas and are considered to be at risk for radiological exposure. In addition, a small fraction of badged visitors may nonroutinely enter radiological areas. Table A.3.2.3-8 provides a breakdown of those employees who may be at risk of radiological exposure. 

Table A.3.2.3-8.-- Lawrence Livermore National Laboratory Secondary and Case Fabrication Surge Operation Workers

Labor Category

Number of Employees

Employees at Risk of Radiological Exposure

Office and clerical120 0
Officials and managers45 10
Operatives330150
Professionals12050
Technicians14540

Total Employees 

760 29 250

Waste Management. Radioactive wastes generated from construction activities would be from the five rooms in Building 332 which must be decontaminated before the installation of new equipment. Included in this waste is some ducting, flooring, equipment that would need to be disposed of, and building partitioning materials. Hazardous waste would consist primarily of lubricants and coolants that would be recycled or disposed of in accordance with RCRA guidelines. Nonhazardous solids include construction debris, metal, containers, and packaging materials. Liquid nonhazardous wastes would be treated locally and discharged to the sanitary sewer or hauled to an offsite facility for treatment and disposal. Wastes generated during replacement secondary fabrication operations include radioactive, mixed, hazardous, and nonhazardous byproducts. Table A.3.2.3-9 provides an estimate of the quantities of these waste categories effluent volumes as a result of secondary fabrication construction and surge operations. Secondary and case fabrication operations would not generate any spent nuclear fuel, HLW, or TRU wastes. 

LLW generated from fabrication activities includes protective clothing, abrasive materials, cutting tools, filters, small equipment, and mop water contaminated with uranium. This waste would be treated by sorting, separation, concentration, and size reduction processes. Processed LLW would be surveyed and shipped to an offsite facility for land disposal. 

Mixed wastes would consist of analytical solutions, wipes and rags with acetronitrile and acetone, and organic wastes contaminated with uranium. These wastes would be packaged and shipped to a DOE waste management facility for temporary storage pending treatment and disposal. 

Hazardous wastes would include analytical solutions, rags with acetonitrile and acetone, coolants, hydraulic fluid, curing agents, epoxy resins, and plastics. These wastes would be managed and shipped to a commercial waste facility for treatment and disposal. 

Nonhazardous (sanitary) wastes would consist of such solid items as office waste, paper, spent tools, and scrap materials. These materials would be hauled to an offsite sanitary landfill for disposal. Sanitary liquids would include sewage waste, uncontaminated process fluids, and mop water. These wastes would be discharged to the local municipal sewage system. 

Table A.3.2.3-9.-- Lawrence Livermore National Laboratory Secondary and Case Fabrication Waste Volumes

Category

Annual Average 
Volume Generated 
from Construction
(m3)

Annual Volume 

Generated from 

Surge Operations 
(m 3 )

Annual Volume 

Effluent from 

Surge Operations 
(m 3 )

Low-Level     
LiquidNone105 None
Solid5370 304
Mixed Low-Level     
LiquidNone550 550
SolidNone12 12
Hazardous     
Liquid11540 540
Solid4118 18
Nonhazardous (Sanitary)     
Liquid5,050102,000 102,000
Solid2,8204,320 4,320
Nonhazardous (Other)     
LiquidIncluded in sanitary Included in sanitaryIncluded in sanitary
Solid2553,200 30  None

Nonhazardous (other) wastes would be collected and examined before being reclaimed for other recycled use or release to the environment. Examples of this type of waste are paper, glass, and recyclable metals.


1 

Building construction key: 

Single story building with: A-1 wood frame, A-2 masonry bearing walls with wood roof framing, A-3 masonry bearing walls with structural steel roof stem, A-4 masonry bearing walls with precast concrete roof system, and A-5 prefabricated metal building with metal wall panels. 

Multistory building with: B-1 reinforced concrete structure with masonry walls, B-2 reinforced concrete and structural steel with masonry walls, B-3 structural steel skeleton with masonry walls, B-4 structural steel skeleton with cement-asbestos wall panels, and B-5 structural steel skeleton with metal wall panels.

2
Not all of Building 9212 is within the DP footprint. 

OR MMES 1996j; ORR 1995a:4.

3
Peak demand is the maximum rate expected.

4
Cubic meters measured at standard temperature and pressure. 

OR MMES 1996j; ORR 1995a:3; ORR 1995a:4 . 

5 

Full-time equivalent. 

Source: OR MMES 1996j; ORR 1995a:3; ORR 1995a:4.

6 

Peak demand is the maximum rate expected during any hour.

7 

Cubic meters measured at standard temperature and pressure. 

OR MMES 1996j; ORR 1995a:3; ORR 1995a:4.

8 

Includes 10 m 3 of classified waste, 40 drums depleted uranium ash from chip oxidation (one 55 gal drum = 0.2 m 3 ), and 1,100 m 3 of unclassified waste.

9 

Assumes 100:1 wastewater to sludge ratio for the treatment of liquid LLW followed by 2:1 for solidification. Assumes 2/3 of LLW is compactible by a factor of 4:1. LLW in drums is not compactible.

10 

Includes 2 m 3 of classified waste and 90 m 3 of unclassified waste.

11 

Y-12 only pretreats industrial wastewater prior to discharge to the city of Oak Ridge Municipal Sanitary Sewer System.

12 

Includes 3.4 m 3 of concrete and 4.1 t of steel.

13 

Includes 5 m 3 of classified waste.

14 

Assumes 2/3 of solid is compactible by a factor of 4:1.

15 

Recyclable wastes. 

OR MMES 1996j; ORR 1995a:4.

16 

Peak demand is the maximum rate expected.

17 

Cubic meters measured at standard temperature and pressure. 

LANL 1995b:4; LANL 1995e.

18 

The total of all criteria pollutants is estimated to be less than 1 metric ton. 

LANL 1995b:4; LANL 1995e.

19 

Peak demand is the maximum rate expected during any hour.

20 

Cubic meters measured at standard temperature and pressure. 

Source: LANL 1995b:4; LANL 1995e.

21 

Total surge employment. Increment to current employment would be 321. 

Source: LANL 1995b:4.

22 

Assumes 2/3 of the solid LLW is compactible by a factor of 4:1. The wastewater to sludge ratio for liquid LLW treatment is 100:1, followed by 2:1 solidification ratio.

23 

Assumes 2/3 of the solid waste is compactible by a factor of 4:1. The wastewater to sludge ratio for liquid sanitary treatment is 350:1.

24 

Includes 300 t of recyclable steel and 18 t of recyclable copper. 

LANL 1995b:4; LANL 1995e.

25 

Peak demand is the maximum rate expected.

26 

Cubic meters measured at standard temperature and pressure. 

LLNL 1995e.

27 

Peak demand is the maximum rate expected during any hour.

28 

Cubic meters measured at standard temperature and pressure. 

LLNL 1995e; LLNL 1995i:3; LLNL 1996i:2.

29 

Total surge employment. Increase to current employment would be 290. 

Source: LLNL 1995e.

30 

Recyclable wastes. 

LLNL 1995e; LLNL 1995i:3.